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| Date | Location | Result | |
| 10/30/2021 | Duluth, MN | Augsburg 3, St. Scholastica 0 (25-16,25-22,25-17) | Box score |
| 10/29/2021 | Saint Peter, MN | Gustavus Adolphus 3, St. Scholastica 0 (25-17,25-17,25-20) | Box score |
| 10/23/2021 | Northfield, MN | UW-Platteville 3, St. Scholastica 1 (25-18,29-27,16-25,25-21) | Box score |
| 10/23/2021 | Northfield, MN | St. Scholastica 3, Carleton 1 (23-25,25-17,29-27,26-24) | Box score |
| 10/22/2021 | Duluth, MN | St. Catherine 3, St. Scholastica 0 (25-12,25-23,25-20) | Box score |
| 10/19/2021 | Duluth, MN | St. Scholastica 3, UW-Superior 0 (25-18,25-16,25-14) | Box score |
| 10/16/2021 | Saint Paul, MN | Macalester 3, St. Scholastica 1 (29-27,23-25,25-20,25-23) | Box score |
| 10/15/2021 | Duluth, MN | Hamline 3, St. Scholastica 2 (23-25,25-22,25-15,23-25,15-9) | Box score |
| 10/9/2021 | St. Paul, MN | Bethel 3, St. Scholastica 0 (25-10,25-17,25-16) | Box score |
| 10/8/2021 | Duluth, MN | St. Scholastica 3, Concordia (MN) 0 (25-13,25-22,25-11) | Box score |
| 10/2/2021 | St. Joseph, MN | St. Scholastica 3, Saint Benedict 1 (25-21,25-20,17-25,25-20) | Box score |
| 10/1/2021 | Winona, MN | Saint Mary's 3, St. Scholastica 1 (25-19,22-25,25-16,25-18) | Box score |
| 9/28/2021 | Duluth, MN | UW-Eau Claire 3, St. Scholastica 0 (25-14,25-22,25-16) | Box score |
| 9/22/2021 | Duluth, MN | St. Olaf 3, St. Scholastica 0 (25-22,25-22,25-19) | Box score |
| 9/18/2021 | Dubuque, IA | Carthage 3, St. Scholastica 0 (25-18,25-20,25-22) | Box score |
| 9/17/2021 | Dubuque, IA | Loras 3, St. Scholastica 0 (25-17,25-22,25-21) | Box score |
| 9/17/2021 | Dubuque, IA | Grinnell 3, St. Scholastica 1 (25-22,18-25,25-20,25-16) | Box score |